Eight new 1-(1H-1,2,4-triazolyl)-1-Cycloalkyl-(Sub)phenylmathanol compounds were synthesized through the reaction of 1-(1H-1,2,4-triazolyl)-1-(sub)benzoyl-cycloalkane with KBH_4, which were identified by IR, ?~1?H NMR, MS and elemental analysis. The reactive properties and spectrum data were also discussed. Biological activity data indicated that some of the above compounds had good inhibitory action on Puccinia recondite in wheat.