沼液中挥发性有机物去除技术及肥效验证
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吉林省重大科技攻关专项(20130204054SF);吉林省科技引导计划(20150412004XH)


Removal technology of volatile organic compounds from biogas slurry and fertilizer efficiency test
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    摘要:

    【目的】筛选具有应用价值的去除沼液挥发性有机物(VOCs)的方法.【方法】通过热处理、活性炭、通气处理、有机溶剂萃取等方法去除沼液中的VOCs.【结果和结论】不同处理方法的VOCs去除效果最好的条件分别为:热处理70 ℃,去除率57.7%;200 mL沼液用12 g活性炭处理,去除率69.9 %;200 mL沼液采用硫酸、氢氧化钠、过氧化氢处理效果最好时的用量均为20 mL,去除率分别为36.4%、39.2%和39.3%.通氮气、空气和臭氧的VOCs去除率分别为53.0%、67.3%和81.7%;三氯甲烷+石油醚萃取,去除率87.4%;通臭氧和有机溶剂萃取处理相结合,沼液中VOCs去除率达到94.1%,效果十分明显,且未影响沼液的肥效,是沼液除味的有效措施.

    Abstract:

    【Objective】To screen out the optimal applicable method to remove volatile organic compounds (VOCs) from biogas slurry. 【Method】Heat treatment,activated carbon,air treatment and organic solvent extraction were adopted to remove VOCs from biogas slurry. 【Result and conclusion】Treatment conditions and the removal rates for different treatment methods with the best removal efficiency were as follows: the temperature for the heat treatment was 70 ℃ and the removal rate of VOCs from biogas slurry was 57.7%; the dosage of activated carbon was 12 g for 200 mL biogas slurry and the removal rate was 69.9%; the dosages of sulfuric acid, sodium hydroxide, hydrogen peroxide, were all 20 mL for 200 mL biogas slurry, while the removal rates were 36.4%, 39.2% and 39.3% respectively; the removal rates for the treatments of nitrogen, air and ozone were 53.0 %, 67.3% and 81.7% respectively. The removal rate of chloroform+petroleum ether extraction could reach 87.4%. The VOCs removal rate could reach 94.1% by combining VOCs ozone with organic solvent extraction,which was effective without affecting fertilizer efficiency.The combined treatment of ozone and organic solvent extraction is the most effective measure for the deodorization of biogas slurry.

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王宇,金生威,鞠天琛,栾晓晨,冯连双,王玉军.沼液中挥发性有机物去除技术及肥效验证[J].华南农业大学学报,2015,36(4):50-54

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  • 收稿日期:2014-05-08
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  • 在线发布日期: 2015-07-10